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Federal (FBISE) · Quarter book test · Free

2nd Year Chemistry 1st Quarter Book Paper

40 marks · 1 hour · 28 questions. Covers: 6 chapters (01. Ethics and Values in Chemistry to 06.The Transition Metals).

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2nd Year Chemistry 1st Quarter Book Paper

2nd Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 40Time: 1 hour

Q1. Multiple choice questions (Attempt all · 12 × 1 = 12)

  1. The high tendency of Be²⁺ to form complexes is due to:
    1. Large size and low charge density
    2. Small size and high charge density
    3. Covalent character
    4. Presence of 3d orbitals
  2. If Kpc > 1, it means the solute is more soluble in:
    1. Organic solvent
    2. Water
    3. Both equally
    4. None of these
  3. If overall E° of reaction is positive, the reaction is:
    1. Not feasible
    2. Feasible
    3. Endothermic only
    4. At equilibrium
  4. Reduction is defined as:
    1. Loss of protons
    2. Gain of electrons
    3. Loss of neutrons
    4. Loss of electrons
  5. Industrial chemicals, if mismanaged, mainly cause:
    1. Environmental pollution
    2. Medical advancements
    3. Higher crop production
    4. Clean energy
  6. The point at which moles of acid = moles of base is called:
    1. Endpoint
    2. Neutral point
    3. Equivalence point
    4. Indicator point
  7. Why is MgSO₄ more soluble than BaSO₄?
    1. Higher lattice energy of BaSO₄
    2. Higher hydration enthalpy of Mg²⁺
    3. Larger ionic size of Ba²⁺
    4. Both (a) and (b)
  8. The bicarbonate buffer system in blood involves:
    1. NH₄OH and NH₄Cl
    2. NaOH and Na₂CO₃
    3. HCl and NaCl
    4. H₂CO₃ and HCO₃⁻
  9. In stability constant expression for [CoCl₄]²⁻, Kstab = ?
    1. [CoCl₄]²⁻ / [Co(H₂O)₆]²⁺ [Cl⁻]⁴
    2. [Co(H₂O)₆]²⁺ / [CoCl₄]²⁻
    3. [Cl⁻]⁴ / [Co(H₂O)₆]²⁺
    4. None
  10. In a redox reaction, the oxidizing agent:
    1. Loses electrons
    2. Gains electrons
    3. Loses protons
    4. Gains protons
  11. Which of the following is a positive impact of chemical substances on human health?
    1. Respiratory diseases
    2. Medical advancements
    3. Water pollution
    4. Soil pollution
  12. The mathematical expression for pH is:
    1. pH = log [H⁺]
    2. pH = –log [H⁺]
    3. pH = log [OH⁻]
    4. pH = –log [OH⁻]

Q2. Short questions (Attempt any 8 of 12 · 8 × 2 = 16)

  1. Compare the ability of Be²⁺ and Ba²⁺ to form complexes.
  2. Why is it important to understand the structure of a scientific argument?
  3. Explain why the equivalence point is above 7 in weak acid–strong base titration.
  4. Differentiate between strong and weak acids using the extent of ionization and Ka.
  5. Differentiate between Lewis acid and Lewis base in complexes.
  6. Give the general form of a displacement reaction.
  7. How does the reaction of Group 2 metals with dilute acids vary down the group?
  8. Explain the role of assumptions in arguments.
  9. Calculate the pH of the following compounds: (i) 10⁻⁴ M KOH (ii) 10⁻¹⁰ M HCl (iii) 10⁻¹⁰ M KOH (iv) 10⁻⁴ M HCl
  10. Discuss the bicarbonate buffer system in blood and its role in maintaining normal blood pH.
  11. Write the expression of Kstab for [CoCl₄]²⁻.
  12. Arrange Zn, Cu, and Mg in order of reactivity.

Q3. Long questions (Attempt any 3 of 4 · 3 × 4 = 12)

  1. Write in detail about the applications of buffer solutions in daily life and industry.
  2. Discuss the terms coordination number, coordination sphere, and charge on coordination sphere with examples.
  3. Discuss the ethical considerations in the production and use of chemical substances.
  4. Balance the following equations by the oxidation number method: HNO₃ + HI → NO₂ + I₂ + H₂O