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Federal (FBISE) · Half book test (board pattern) · Free

2nd Year Chemistry First half Book Paper

85 marks · 3 hours (Section A: 25 minutes) · 40 questions. Covers: 12 chapters (01. Ethics and Values in Chemistry to 12. Nitrogen Compounds).

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2nd Year Chemistry First half Book Paper

2nd Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 85Time: 3 hours (Section A: 25 minutes)

Q1. Multiple choice questions (Attempt all · 17 × 1 = 17)

  1. Reduction is defined as:
    1. Loss of protons
    2. Gain of electrons
    3. Loss of neutrons
    4. Loss of electrons
  2. Ethanoic acid is oxidized to carbon dioxide and water by:
    1. Fehling’s solution
    2. KMnO₄
    3. Tollen’s reagent
    4. HCl
  3. The point at which moles of acid = moles of base is called:
    1. Endpoint
    2. Neutral point
    3. Equivalence point
    4. Indicator point
  4. (+)-Ibuprofen is:
    1. Inactive
    2. Active
    3. Toxic
    4. Neutral
  5. What is the product when phenylamine reacts with HNO₂ or NaNO₂ and dilute acid below 10°C?
    1. Aniline
    2. Phenol
    3. Benzene diazonium chloride
    4. Nitrobenzene
  6. If overall E° of reaction is positive, the reaction is:
    1. Not feasible
    2. Feasible
    3. Endothermic only
    4. At equilibrium
  7. Which aromatic compound is used as an antiseptic?
    1. Nitrobenzene
    2. Phenol
    3. Styrene
    4. Anisole
  8. The high tendency of Be²⁺ to form complexes is due to:
    1. Large size and low charge density
    2. Small size and high charge density
    3. Covalent character
    4. Presence of 3d orbitals
  9. If Kpc > 1, it means the solute is more soluble in:
    1. Organic solvent
    2. Water
    3. Both equally
    4. None of these
  10. Reaction of acyl chloride with primary amines produces:
    1. N-substituted amides
    2. Alcohols
    3. Esters
    4. Aldehydes
  11. Industrial chemicals, if mismanaged, mainly cause:
    1. Environmental pollution
    2. Medical advancements
    3. Higher crop production
    4. Clean energy
  12. Chlorobenzene undergoes which type of reaction?
    1. Nucleophilic substitution
    2. Electrophilic substitution
    3. Elimination reaction
    4. Hydrolysis
  13. In a redox reaction, the oxidizing agent:
    1. Loses electrons
    2. Gains electrons
    3. Loses protons
    4. Gains protons
  14. How does chlorine substitution affect the acidity of carboxylic acids?
    1. It increases acidity by donating electrons
    2. It decreases acidity by withdrawing electrons
    3. It increases acidity by withdrawing electrons
    4. It increases acidity by withdrawing hydrogen
  15. The mathematical expression for pH is:
    1. pH = log [H⁺]
    2. pH = –log [H⁺]
    3. pH = log [OH⁻]
    4. pH = –log [OH⁻]
  16. Geometric isomerism is shown by
    1. alkenes
    2. alkynes
    3. alkanes
    4. lkanes
  17. Phenol is more reactive than benzene because:
    1. –OH group withdraws electrons
    2. –OH group donates electrons to ring
    3. –OH group forms aldehyde
    4. –OH group oxidizes rapidly

Q2. Short questions (Attempt any 7 of 10 · 7 × 3 = 21)

  1. Give the general form of a displacement reaction.
  2. Explain why the equivalence point is above 7 in weak acid–strong base titration.
  3. Why is it important to understand the structure of a scientific argument?
  4. Differentiate between strong and weak acids using the extent of ionization and Ka.
  5. Differentiate between Lewis acid and Lewis base in complexes.
  6. Compare the ability of Be²⁺ and Ba²⁺ to form complexes.
  7. Arrange Zn, Cu, and Mg in order of reactivity.
  8. Calculate the pH of the following compounds: (i) 10⁻⁴ M KOH (ii) 10⁻¹⁰ M HCl (iii) 10⁻¹⁰ M KOH (iv) 10⁻⁴ M HCl
  9. Explain the role of assumptions in arguments.
  10. Discuss the bicarbonate buffer system in blood and its role in maintaining normal blood pH.

Q3. Short questions (Attempt any 7 of 10 · 7 × 3 = 21)

  1. Why do aryl chlorides resist hydrolysis?
  2. Why does benzene not behave like an alkene?
  3. Differentiate between primary, secondary, and tertiary alkyl halides.
  4. Why is HCN not used directly in reactions?
  5. Write the chemical equation for the reaction of phenol with sodium hydroxide.
  6. Define racemic mixture.
  7. Explain why methanoic acid can be oxidized while other carboxylic acids cannot.
  8. Write the product of reaction of benzene with CH₃COCl in presence of AlCl₃.
  9. Define haloarenes with an example.
  10. Give the equation for the reduction of ethanamide.

Q4. Long questions (Attempt any 2 of 3 · 2 × 13 = 26)

  1. Explain the mechanisms of Sₙ₁ and Sₙ₂ reactions in detail, including the factors that affect each mechanism and examples of substrates that prefer each pathway.
  2. Describe the reduction of nitriles to form amines. Support with chemical reactions.
  3. Discuss the titration curve of weak acid–weak base and explain why no sharp equivalence point is obtained.