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2nd Year Chemistry First half Book Paper2nd Year · Chemistry · Federal (FBISE)
Q1. Multiple choice questions (Attempt all · 17 × 1 = 17)
- Reduction is defined as:
- Ethanoic acid is oxidized to carbon dioxide and water by:
- The point at which moles of acid = moles of base is called:
- (+)-Ibuprofen is:
- What is the product when phenylamine reacts with HNO₂ or NaNO₂ and dilute acid below 10°C?
- If overall E° of reaction is positive, the reaction is:
- Which aromatic compound is used as an antiseptic?
- The high tendency of Be²⁺ to form complexes is due to:
- If Kpc > 1, it means the solute is more soluble in:
- Reaction of acyl chloride with primary amines produces:
- Industrial chemicals, if mismanaged, mainly cause:
- Chlorobenzene undergoes which type of reaction?
- In a redox reaction, the oxidizing agent:
- How does chlorine substitution affect the acidity of carboxylic acids?
- The mathematical expression for pH is:
- Geometric isomerism is shown by
- Phenol is more reactive than benzene because:
Q2. Short questions (Attempt any 7 of 10 · 7 × 3 = 21)
- Give the general form of a displacement reaction.
- Explain why the equivalence point is above 7 in weak acid–strong base titration.
- Why is it important to understand the structure of a scientific argument?
- Differentiate between strong and weak acids using the extent of ionization and Ka.
- Differentiate between Lewis acid and Lewis base in complexes.
- Compare the ability of Be²⁺ and Ba²⁺ to form complexes.
- Arrange Zn, Cu, and Mg in order of reactivity.
- Calculate the pH of the following compounds: (i) 10⁻⁴ M KOH (ii) 10⁻¹⁰ M HCl (iii) 10⁻¹⁰ M KOH (iv) 10⁻⁴ M HCl
- Explain the role of assumptions in arguments.
- Discuss the bicarbonate buffer system in blood and its role in maintaining normal blood pH.
Q3. Short questions (Attempt any 7 of 10 · 7 × 3 = 21)
- Why do aryl chlorides resist hydrolysis?
- Why does benzene not behave like an alkene?
- Differentiate between primary, secondary, and tertiary alkyl halides.
- Why is HCN not used directly in reactions?
- Write the chemical equation for the reaction of phenol with sodium hydroxide.
- Define racemic mixture.
- Explain why methanoic acid can be oxidized while other carboxylic acids cannot.
- Write the product of reaction of benzene with CH₃COCl in presence of AlCl₃.
- Define haloarenes with an example.
- Give the equation for the reduction of ethanamide.
Q4. Long questions (Attempt any 2 of 3 · 2 × 13 = 26)
- Explain the mechanisms of Sₙ₁ and Sₙ₂ reactions in detail, including the factors that affect each mechanism and examples of substrates that prefer each pathway.
- Describe the reduction of nitriles to form amines. Support with chemical reactions.
- Discuss the titration curve of weak acid–weak base and explain why no sharp equivalence point is obtained.