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Federal (FBISE) · Chapter test · Free

1st Year Chemistry Chapter 7 Test07. chemical Kinetics

30 marks · 40 minutes · 21 questions. Covers: 07. chemical Kinetics.

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1st Year Chemistry Chapter 7 Test

1st Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 30Time: 40 minutes

Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)

  1. The activation energy for a reaction can be:
    1. Increased by increasing temprature
    2. Increased by decreasing temprature
    3. Decreased by increasing concentration of reactants
    4. None of these
  2. In a graph of concentration vs. time, the slope of the curve represents:
    1. Activation energy
    2. Rate of reaction
    3. Temperature
    4. Pressure
  3. The rate of reaction generally increases with:
    1. Increase in temperature
    2. Decrease in temperature
    3. Constant temperature
    4. Cooling
  4. If the concentration of C changes from 0.0 to 0.38 mol dm⁻³ in 20 s, the rate of reaction is approximately:
    1. 0.38 mol dm⁻³ s⁻¹
    2. 0.45 mol dm⁻³ s⁻¹
    3. 0.20 mol dm⁻³ s⁻¹
    4. 0.019 mol dm⁻³ s⁻¹
  5. Activation energy is represented by the symbol:
    1. Ea
    2. ∆H
    3. Ep
    4. Et
  6. The rate equation Rate=k[CH₃Cl][Cl₂]½ represents:
    1. First order
    2. Second order
    3. Fractional order
    4. Third order
  7. In the expression A→B, the rate can be written as:
    1. dx/dt = -d[A]/dt = +d[B]/dt
    2. dx/dt = -d[B]/dt
    3. dx/dt = +d[A]/dt
    4. None of these
  8. The rate equation for 2NO₂+F₂→2NO₂F is:
    1. Rate=k[NO₂]²
    2. Rate=k[F₂]
    3. Rate=k[NO₂][F₂]
    4. Rate=k[NO₂F]
  9. The reaction NO+O₃→NO₂+O₂ follows which order?
    1. First order
    2. Second order
    3. Third order
    4. Fractional order
  10. For a first-order reaction, rate is proportional to:
    1. [A]²
    2. 1/[A]
    3. [A]⁰
    4. [A]¹

Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)

  1. What are effective collisions?
  2. Explain the meaning of "elementary step."
  3. Why does a slow step determine the overall reaction rate?
  4. Write the mechanism for the reaction NO₂+CO→NO+CO₂.
  5. Define catalyst and catalysis.
  6. Write the relationship between half-life and rate constant for second-order reaction.
  7. What is a reaction intermediate?
  8. Write the mechanism for the decomposition of hypochlorite ion 3ClO⁻→ClO₃⁻+2Cl⁻.

Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)

  1. Explain activation energy and effective collision theory. Illustrate your answer with a potential energy diagram.
  2. For the reaction: A + B → AB. The following data were obtained for the reaction:ExperimentInitial conc. (mole dm−3) [A]Initial conc. (mole dm−3) [B]Initial rate (moldm−3 s−1)10.100.011.00×10−520.100.022.00×10−530.200.012.00×10−540.300.026.00×10−5\begin{array}{|c|c|c|c|} \hline \text{Experiment} & \text{Initial conc. (mole dm}^{-3}\text{) [A]} & \text{Initial conc. (mole dm}^{-3}\text{) [B]} & \text{Initial rate (moldm}^{-3}\text{ s}^{-1}\text{)} \\ \hline 1 & 0.10 & 0.01 & 1.00 \times 10^{-5} \\ \hline 2 & 0.10 & 0.02 & 2.00 \times 10^{-5} \\ \hline 3 & 0.20 & 0.01 & 2.00 \times 10^{-5} \\ \hline 4 & 0.30 & 0.02 & 6.00 \times 10^{-5} \\ \hline \end{array} What is the rate equation for the reaction?
  3. Explain effects of concentration and surface area on reaction rates.