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Federal (FBISE) · Chapter test · Free

2nd Year Chemistry Chapter 11 Test11. Carbonyl Compounds

30 marks · 40 minutes · 21 questions. Covers: 11. Carbonyl Compounds.

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2nd Year Chemistry Chapter 11 Test

2nd Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 30Time: 40 minutes

Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)

  1. Ethanoic acid is oxidized to carbon dioxide and water by:
    1. Fehling’s solution
    2. KMnO₄
    3. Tollen’s reagent
    4. HCl
  2. How does chlorine substitution affect the acidity of carboxylic acids?
    1. It increases acidity by donating electrons
    2. It decreases acidity by withdrawing electrons
    3. It increases acidity by withdrawing electrons
    4. It increases acidity by withdrawing hydrogen
  3. Which ion is produced when carboxylic acids dissolve in water?
    1. OH⁻
    2. Cl⁻
    3. H⁺
    4. Na⁺
  4. The reactivity of carboxylic acids is mainly due to the presence of:
    1. Hydroxyl group
    2. Carbonyl group
    3. Alkyl group
    4. Aryl group
  5. In aldehydes, the carbonyl group is attached to:
    1. Two alkyl groups
    2. One hydrogen and an alkyl group
    3. Two aryl groups
    4. One hydroxyl group
  6. The relative acidity of chlorinated carboxylic acids is primarily due to:
    1. Increased stability of the conjugate base
    2. Electron-donating effects of the chlorine atom
    3. Lowering of the carboxylate pKₐ
    4. Increased electron density around the carbonyl group
  7. Which of the following acyl chlorides is expected to hydrolyze most readily?
    1. Methyl chloride
    2. Acetyl chloride
    3. Phenyl chloride
    4. Benzyl chloride
  8. Which test can oxidize methanoic acid to produce a silver mirror?
    1. Fehling’s solution
    2. Tollen’s reagent
    3. Benedict’s solution
    4. Iodine solution
  9. In most reactions of carboxylic acids:
    1. The hydroxyl group is lost
    2. The carboxyl group is retained
    3. The alkyl group reacts
    4. The carbonyl group is destroyed
  10. Which compound is the strongest acid among the following?
    1. Ethanol
    2. Phenol
    3. Ethanoic acid
    4. Methanol

Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)

  1. Why do aryl chlorides resist hydrolysis?
  2. Explain why methanoic acid can be oxidized while other carboxylic acids cannot.
  3. Write the reaction of carboxylic acid with SOCl₂.
  4. Write the general formula of aldehydes and ketones.
  5. Describe the mechanism of acyl chloride hydrolysis with water.
  6. Why is hot alkaline KMnO₄ used in the oxidation of alkyl benzenes?
  7. Which oxidizing agent converts methanoic acid into CO₂ and H₂O with silver mirror formation?
  8. What products are formed when ethanedioic acid is oxidized with warm acidified KMnO₄?

Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)

  1. Compare the hydrolysis of acyl, alkyl, and aryl chlorides. Explain with reasons for differences in reactivity.
  2. Describe the process of converting toluene to benzoic acid using hot alkaline KMnO₄ and then dilute acid. Include the mechanism and discuss the reasons for the choice of reagent.
  3. Explain the dual reactivity of carboxylic acids due to the presence of both carbonyl (C=O) and hydroxyl (–OH) groups.