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2nd Year Chemistry Chapter 11 Test2nd Year · Chemistry · Federal (FBISE)
Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)
- Ethanoic acid is oxidized to carbon dioxide and water by:
- How does chlorine substitution affect the acidity of carboxylic acids?
- Which ion is produced when carboxylic acids dissolve in water?
- The reactivity of carboxylic acids is mainly due to the presence of:
- In aldehydes, the carbonyl group is attached to:
- The relative acidity of chlorinated carboxylic acids is primarily due to:
- Which of the following acyl chlorides is expected to hydrolyze most readily?
- Which test can oxidize methanoic acid to produce a silver mirror?
- In most reactions of carboxylic acids:
- Which compound is the strongest acid among the following?
Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)
- Why do aryl chlorides resist hydrolysis?
- Explain why methanoic acid can be oxidized while other carboxylic acids cannot.
- Write the reaction of carboxylic acid with SOCl₂.
- Write the general formula of aldehydes and ketones.
- Describe the mechanism of acyl chloride hydrolysis with water.
- Why is hot alkaline KMnO₄ used in the oxidation of alkyl benzenes?
- Which oxidizing agent converts methanoic acid into CO₂ and H₂O with silver mirror formation?
- What products are formed when ethanedioic acid is oxidized with warm acidified KMnO₄?
Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)
- Compare the hydrolysis of acyl, alkyl, and aryl chlorides. Explain with reasons for differences in reactivity.
- Describe the process of converting toluene to benzoic acid using hot alkaline KMnO₄ and then dilute acid. Include the mechanism and discuss the reasons for the choice of reagent.
- Explain the dual reactivity of carboxylic acids due to the presence of both carbonyl (C=O) and hydroxyl (–OH) groups.