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Federal (FBISE) · Chapter test · Free

2nd Year Chemistry Chapter 6 Test06.The Transition Metals

30 marks · 40 minutes · 21 questions. Covers: 06.The Transition Metals.

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2nd Year Chemistry Chapter 6 Test

2nd Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 30Time: 40 minutes

Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)

  1. If overall E° of reaction is positive, the reaction is:
    1. Not feasible
    2. Feasible
    3. Endothermic only
    4. At equilibrium
  2. In stability constant expression for [CoCl₄]²⁻, Kstab = ?
    1. [CoCl₄]²⁻ / [Co(H₂O)₆]²⁺ [Cl⁻]⁴
    2. [Co(H₂O)₆]²⁺ / [CoCl₄]²⁻
    3. [Cl⁻]⁴ / [Co(H₂O)₆]²⁺
    4. None
  3. Which transition metal is used in aircraft and artificial joints?
    1. Iron
    2. Titanium
    3. Copper
    4. Zinc
  4. Which type of isomerism is shown by [Pt(NH₃)₂Cl₂]?
    1. Ionization isomerism
    2. Hydrate isomerism
    3. Geometric isomerism
    4. Optical isomerism
  5. Overall standard potential for Cu²⁺ + I⁻ reaction is:
    1. Positive
    2. Zero
    3. Neutral
    4. Negative
  6. In the reaction of MnO₄⁻ with ethanedioate (C₂O₄²⁻), MnO₄⁻ is:
    1. Oxidized to MnO₂
    2. Reduced to Mn²⁺
    3. Oxidized to Mn³⁺
    4. Oxidized to Mn³⁺
  7. Which transition element has the lowest melting point?
    1. Iron
    2. Zinc
    3. Titanium
    4. Chromium
  8. The feasibility of Cu²⁺ + I⁻ reaction occurs due to:
    1. Positive E° value
    2. Precipitation of CuI
    3. Liberation of CO₂
    4. Formation of Mn²⁺
  9. Which factor stabilizes variable oxidation states of transition elements?
    1. Low ionization enthalpy
    2. High electronegativity
    3. Half-filled/fully filled subshells
    4. Large atomic size
  10. The colour of complexes is due to:
    1. Transfer of protons
    2. d–d electronic transitions
    3. Ionization of ligands
    4. Strong oxidation

Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)

  1. Differentiate between Lewis acid and Lewis base in complexes.
  2. Write the expression of Kstab for [CoCl₄]²⁻.
  3. How does concentrated HCl affect cobalt(II) aqueous complexes?
  4. Define ligand substitution reaction.
  5. What are eg and t2g sets in octahedral complexes?
  6. Why do transition metals show variable oxidation states?
  7. Define transition elements.
  8. Write the name of [Cu(NH₃)₄]SO₄.

Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)

  1. Discuss the terms coordination number, coordination sphere, and charge on coordination sphere with examples.
  2. What are ligands? Discuss types of ligands with examples and structures.
  3. Explain the method of predicting feasibility of redox reactions using standard electrode potentials with examples.