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2nd Year Chemistry Chapter 18 Test2nd Year · Chemistry · Federal (FBISE)
Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)
- Spectroscopy is based on the interaction of atoms or molecules with:
- The property that makes nuclei NMR active is called:
- Which isotopes are commonly used in NMR studies?
- Why is ¹³C NMR possible while ¹²C NMR is not?
- The typical IR range used for organic compounds is:
- Approximately what percentage of natural carbon atoms are ¹³C?
- Spectroscopy is a technique in which matter interacts with:
- An atomic absorption spectrum is produced when atoms in the ground state:
- In Atomic Emission Spectroscopy (AES), spectral lines appear as:
- The energy difference between the two spin states corresponds to:
Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)
- What is the effect of external magnetic field on the spinning nuclei?
- What is deuterium exchange method and what is its use?
- What are spectral lines?
- What is proton NMR spectroscopy?
- Why deuterated solvents are used in proton NMR spectroscopy?
- Why is each element said to have a unique emission spectrum?
- Define atomic absorption spectrum.
- Why does acetone give a single peak in proton-NMR and two peaks in 13C-NMR? Explain with reason.
Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)
- Explain the concept of index of hydrogen deficiency (IHD).
- Explain the working principle of NMR spectroscopy and describe how resonance occurs.
- Explain the principle of ¹³C NMR spectroscopy. Discuss chemical shift and its importance in structure elucidation.