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Federal (FBISE) · Chapter test · Free

2nd Year Chemistry Chapter 18 Test18. Spectroscopy

30 marks · 40 minutes · 21 questions. Covers: 18. Spectroscopy.

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2nd Year Chemistry Chapter 18 Test

2nd Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 30Time: 40 minutes

Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)

  1. Spectroscopy is based on the interaction of atoms or molecules with:
    1. Heat
    2. Sound waves
    3. Electromagnetic radiations
    4. Chemical reactions
  2. The property that makes nuclei NMR active is called:
    1. Isotopic mass
    2. Spin
    3. Charge density
    4. Energy difference
  3. Which isotopes are commonly used in NMR studies?
    1. H¹ and C¹²
    2. H¹ and C¹³
    3. O¹⁶ and N¹⁴
    4. H² and C¹⁴
  4. Why is ¹³C NMR possible while ¹²C NMR is not?
    1. ¹²C is radioactive
    2. ¹³C has non-zero nuclear spin
    3. ¹³C is more abundant
    4. ¹²C has strong magnetic properties
  5. The typical IR range used for organic compounds is:
    1. 200–400 cm⁻¹
    2. 4000–625 cm⁻¹
    3. 10000–5000 cm⁻¹
    4. 1–100 cm⁻¹
  6. Approximately what percentage of natural carbon atoms are ¹³C?
    1. 0.0001
    2. 0.01
    3. 0.1
    4. 0.5
  7. Spectroscopy is a technique in which matter interacts with:
    1. Light
    2. Sulphuric acid
    3. Magnetic field
    4. Plasma
  8. An atomic absorption spectrum is produced when atoms in the ground state:
    1. Emit light at specific wavelengths
    2. Absorb light at specific wavelengths
    3. Scatter incoming radiation
    4. Reflect visible light
  9. In Atomic Emission Spectroscopy (AES), spectral lines appear as:
    1. Dark lines on bright background
    2. Bright lines on dark background
    3. Coloured bands
    4. Continuous spectrum
  10. The energy difference between the two spin states corresponds to:
    1. X-ray frequency
    2. UV frequency
    3. Radio wave frequency
    4. Infrared frequency

Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)

  1. What is the effect of external magnetic field on the spinning nuclei?
  2. What is deuterium exchange method and what is its use?
  3. What are spectral lines?
  4. What is proton NMR spectroscopy?
  5. Why deuterated solvents are used in proton NMR spectroscopy?
  6. Why is each element said to have a unique emission spectrum?
  7. Define atomic absorption spectrum.
  8. Why does acetone give a single peak in proton-NMR and two peaks in 13C-NMR? Explain with reason.

Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)

  1. Explain the concept of index of hydrogen deficiency (IHD).
  2. Explain the working principle of NMR spectroscopy and describe how resonance occurs.
  3. Explain the principle of ¹³C NMR spectroscopy. Discuss chemical shift and its importance in structure elucidation.