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Federal (FBISE) · Chapter test · Free

2nd Year Chemistry Chapter 8 Test08. Hydrocarbons

30 marks · 40 minutes · 21 questions. Covers: 08. Hydrocarbons.

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2nd Year Chemistry Chapter 8 Test

2nd Year · Chemistry · Federal (FBISE)

Name: ____________Roll No: ________Class/Section: ________Date: ________Total marks: 30Time: 40 minutes

Q1. Multiple choice questions (Attempt all · 10 × 1 = 10)

  1. Which aromatic compound is used as an antiseptic?
    1. Nitrobenzene
    2. Phenol
    3. Styrene
    4. Anisole
  2. Benzene is generally resistant to oxidation because of its:
    1. Saturated bonds
    2. Delocalized π-electrons
    3. Presence of hydrogen
    4. Weak σ-bonds
  3. The actual heat of hydrogenation of benzene is:
    1. –120 kJ/mol
    2. –208 kJ/mol
    3. –360 kJ/mol
    4. –152 kJ/mol
  4. Oxidizing agent commonly used for oxidation of side chain in alkylbenzenes:
    1. HCl
    2. KMnO₄
    3. H₂SO₄
    4. NaCl
  5. Kekulé’s dream about benzene structure included:
    1. Chains breaking
    2. Snakes biting their tails
    3. Hexagons glowing
    4. Circles joining hands
  6. Nitration of benzene gives:
    1. Nitrobenzene
    2. Benzyl nitrate
    3. Phenol
    4. Toluene
  7. Friedel-Crafts alkylation introduces:
    1. NO₂ group
    2. Halogen
    3. Alkyl group
    4. –OH group
  8. Catalyst in Friedel-Crafts reaction:
    1. H₂SO₄
    2. AlCl₃
    3. FeX₃
    4. Ni
  9. Benzene was first obtained by distilling:
    1. Coal tar
    2. Benzoin resin
    3. Animal fat
    4. Petroleum
  10. Substituents that increase reactivity of benzene ring are called:
    1. Activating groups
    2. Deactivating groups
    3. Saturating groups
    4. Oxidizing groups

Q2. Short questions (Attempt any 6 of 8 · 6 × 2 = 12)

  1. Why does benzene not behave like an alkene?
  2. Write the product of reaction of benzene with CH₃COCl in presence of AlCl₃.
  3. Give mechanism of chlorination.
  4. Write catalyst used in halogenation of benzene.
  5. Why is benzene resistant to oxidation?
  6. Define meta-directing groups. Give one example.
  7. What was Kekulé’s dream, and how did it influence his model?
  8. Name the three steps of electrophilic substitution mechanism.

Q3. Long questions (Attempt any 2 of 3 · 2 × 4 = 8)

  1. Explain with mechanism why electron-donating groups are ortho/para directing in benzene.
  2. A nitrobenzene undergoes nitration much more slowly than benzene. Explain why this happens and predict how the rate would change if a methoxy group were present instead.
  3. Describe Kekulé’s structure of benzene. Why was it important in the history of chemistry?